称取含有PbO和PbO2的试样1.234g,用20.00mL0.2500mol/LH2C2O4溶液处理,此时Pb(Ⅳ)被还原为Pb2+,将溶液中和,使Pb2+定量沉淀为PbC2O2,过滤,将滤液酸化,以c(1/5KMnO4)=0.2000mol/LKMnO4标准滴定溶液滴定,用去10.00mL。沉淀以酸溶解,用相同浓度KMnO4滴定,消耗30.00mL,则试样中PbO2的含量为()。已知:M(PbO)=223.2g/mol,M(PbO2)=239.0g/mol。
- A9.68%
- B19.37%
- C36.18%
- D38.74%